2001-2005

6. “New Linear High-Valent Tetranuclear Manganese-Oxo Cluster Relevant to the Oxygen-Evolving Complex of Photosystem II with Oxo, Hydroxo and Aqua Coordinated to a Single Mn(IV)”, Hongyu Chen, Marie N. Collomb, Carole Duboc, Genevieve Blondin, Eric. Rivière, J. W. Faller, Robert H. Crabtree* and Gary W. Brudvig*, Inorganic Chemistry, 2005, 44(25), 9567-9573.link



5. “General Synthesis of Di-μ-oxo Dimanganese Complexes as Functional Models for the Oxygen Evolving Complex of Photosystem II”, Hongyu Chen, Ranitendranath Tagore, Siddhartha Das, Christopher Incarvito, J. W. Faller, Robert H. Crabtree* and Gary W. Brudvig*, Inorganic Chemistry, 2005, 44(21), 7661-7670.link



4. “High-Spin Chloro Mononuclear MnIII Complexes: A Multifrequency High-Field EPR Study”, Claire Mantel, Hongyu Chen, Robert H. Crabtree, Gary W. Brudvig, Jacques Pécaut, Marie N. Collomb* and Carole Duboc*, ChemPhysChem, 2005, 6(3), 541-546.link



3. “Dimer-of-Dimers Model for the Oxygen-Evolving Complex of Photosystem II. Synthesis and Properties of [MnIV4O5(terpy)4(H2O)2](ClO4)6”, Hongyu Chen, J. W. Faller, Robert H. Crabtree* and Gary W. Brudvig*, Journal of the American Chemical Society, 2004, 126(23), 7345-7349.link



2. “Electrochemical properties of [MnIII(terpy)(N3)3] (terpy=2,2':6',2''-terpyridine) in CH3CN ¾¾ Electrogeneration of dimanganese(II) di-m-azido and dimanganese(IV) di-m-oxo complexes”, Carole Baffert, Hongyu Chen, Robert H. Crabtree, Gary W. Brudvig* and Marie N. Collomb*, Journal of Electroanalytical Chemistry, 2001, 506(2), 99-105.link



1. “Characterization of the O2-evolving reaction catalyzed by [(terpy)(H2O)MnIII(m-O)2MnIV(OH2)(terpy)](NO3)3 (terpy = 2,2':6,2''-terpyridine)”, Julian Limburg, John S. Vrettos, Hongyu Chen, Julio C. de Paula, Robert H. Crabtree* and Gary W. Brudvig*, Journal of the American Chemical Society, 2001, 123(3), 423-430.link